+DIREKTIVA 2008/105/EZ EUROPSKOG PARLAMENTA I VIJEĆA od 16. prosinca 2008. o standardima kvalitete okoliša u području vodne politike i o izmjeni i kasnijem stavljanju izvan snage Direktiva Vijeća 82/176/EEZ, 83/513/EEZ, 84/156/EEZ, 84/491/EEZ, 86/280EEZ i izmjeni Direktive 2000/60/EZ Europskog parlamenta i Vijeća
---+Članak 1. Predmet
---+Članak 2. Definicije
---+Članak 3. Standardi kvalitete okoliša (SKO-i)
------+Article 3 1.
------+Article 3 1a.
------+Article 3 1b.
------+Article 3 2.
------+Article 3 3.
------+Article 3 3a.
------+Article 3 3b.
------+Article 3 4.
------+Article 3 5.
------+Article 3 5a.
------+Article 3 6.
------+Article 3 8.
------+Article 3 8a.
------+Article 3 8b.
---+Članak 4. Zone miješanja
------+Article 4 1.
------+Article 4 2.
------+Article 4 3.
---+Članak 5. Inventar emisija, ispuštanja i gubitaka
------+Article 5 1.
------+Article 5 2.
------+Article 5 3.
---+Članak 6. Prekogranično onečišćenje
------+Article 6 1.
------+Article 6 2.
---+Članak 7. Izvješćivanje i preispitivanje
------+Article 7 1.
------+Article 7 2.
---+Article 7a Coordination
------+Article 7a 1.
------+Article 7a 2.
------+Article 7a 3.
---+Članak 8. Preispitivanje Priloga X. Direktivi 2000/60/EZ
------+Article 8 1.
------+Article 8 2.
------+Article 8 3.
---+Article 8a Specific provisions for certain substances
------+Article 8a 1.
------+Article 8a 2.
------+Article 8a 3.
------+Article 8a 4.
------+Article 8a 5.
---+Article 8b Watch list
------+Article 8b 1.
------+Article 8b 1a.
------+Article 8b 1b.
------+Article 8b 1c.
------+Article 8b 2.
------+Article 8b 3.
------+Article 8b 4.
------+Article 8b 5.
---+Article 8c Specific provisions for pharmaceutical substances
---+Article 8d River basin specific pollutants
------+Article 8d 1.
------+Article 8d 2.
------+Article 8d 3.
---+Članak 9. Postupak Odbora
------+Article 9 1.
------+Article 9 2.
---+Article 9a Exercise of the delegation
------+Article 9a 1.
------+Article 9a 2.
------+Article 9a 3.
------+Article 9a 3a.
------+Article 9a 4.
------+Article 9a 5.
---+Članak 11. Izmjena Direktiva 82/176/EEZ, 83/513/EEZ, 84/156/EEZ, 84/491/EEZ i 86/280/EEZ
------+Article 11 1.
------+Article 11 2.
---+Članak 12. Stavljanje izvan snage Direktiva 82/176/EEZ, 83/513/EEZ, 84/156/EEZ, 84/491/EEZ i 86/280/EEZ
------+Article 12 1.
------+Article 12 2.
---+Članak 13. Prenošenje
------+Article 13 1.
------+Article 13 2.
---+Članak 14. Stupanje na snagu
---+Članak 15. Adresati
---+ANNEX I
---+ANNEX II ENVIRONMENTAL QUALITY STANDARDS FOR RIVER BASIN SPECIFIC POLLUTANTS
---+ANNEX III SUBSTANCES SUBJECT TO REVIEW FOR POSSIBLE IDENTIFICATION AS PRIORITY SUBSTANCES
|
English -
European Union -
Environment -
DIREKTIVA 2008/105/EZ EUROPSKOG PARLAMENTA I VIJEĆA od 16. prosinca 2008. o standardima kvalitete okoliša u području vodne politike i o izmjeni i kasnijem stavljanju izvan snage Direktiva Vijeća 82/176/EEZ, 83/513/EEZ, 84/156/EEZ, 84/491/EEZ, 86/280EEZ i izmjeni Direktive 2000/60/EZ Europskog parlamenta i Vijeća
DIREKTIVA 2008/105/EZ EUROPSKOG PARLAMENTA I VIJEĆA
od 16. prosinca 2008. o standardima kvalitete okoliša u području vodne politike i o izmjeni i kasnijem stavljanju izvan snage Direktiva Vijeća 82/176/EEZ, 83/513/EEZ, 84/156/EEZ, 84/491/EEZ, 86/280EEZ i izmjeni Direktive 2000/60/EZ Europskog parlamenta i Vijeća 1. Pregled
| Naslov |
Regulativa |
|
Članak 1. Predmet
|
Članak 1. Predmet Ovom se Direktivom utvrđuju standardi kvalitete okoliša (SKO-i) za prioritetne tvari i neke druge onečišćujuće tvari, kako je predviđeno u članku 16. Direktive 2000/60/EZ, s ciljem postizanja dobrog kemijskog stanja površinskih voda, a u skladu s odredbama i ciljevima iz članka 4. te Direktive. |
|
Članak 2. Definicije
|
Članak 2. Definicije Za potrebe ove Direktive primjenjuju se definicije utvrđene u članku 2. Direktive 2000/60/EZ. |
|
Članak 3. Standardi kvalitete okoliša (SKO-i)
|
Standardi kvalitete okoliša (SKO-i) 1. U skladu s člankom 1. ove Direktive i člankom 4. Direktive 2000/60/EZ, države članice primjenjuju SKO-e za vodna tijela površinskih voda, utvrđene u dijelu A Priloga I. ovoj Direktivi. Za vodna tijela površinskih voda države članice primjenjuju SKO-e u skladu sa zahtjevima utvrđenima u dijelu B Priloga I. 2. Države članice mogu se odlučiti za primjenu SKO-a za sedimente i/ili biotu umjesto SKO-a utvrđenih u dijelu A Priloga I. za neke kategorije površinskih voda. Države članice koje koriste ovu opciju:
|
|
Članak 4. Zone miješanja
|
Zone miješanja 1. Države članice mogu odrediti zone miješanja u blizini točaka ispuštanja. Koncentracije jedne ili više tvari navedenih u dijelu A Priloga I. smiju biti više od relevantnih SKO-a u području zona miješanja ako ne utječu na usklađenost ostatka vodnog tijela površinskih voda s tim standardima. 2. Države članice koje određuju zone miješanja moraju u planove upravljanja vodnim područjima u skladu s člankom 13. Direktive 2000/60/EZ uključiti opis:
|
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Članak 5. Inventar emisija, ispuštanja i gubitaka
|
Članak 5. Inventar emisija, ispuštanja i gubitaka 1. Na temelju informacija prikupljenih u skladu s člancima 5. i 8. Direktive 2000/60/EZ, prema Uredbi (EZ) br. 166/2006 i dugim raspoloživim podacima, države članice sastavljaju inventar emisija, ispuštanja i gubitaka svih prioritetnih tvari i onečišćujućih tvari navedenih u dijelu A Priloga I. ovoj Direktivi, uključujući po mogućnosti i karte za svako vodno područje ili dio vodnog područja koje se nalazi na njihovom državnom području, navodeći, prema potrebi, njihove koncentracije u sedimentima i bioti. 2. Referentno razdoblje za procjenu vrijednosti onečišćujućih tvari koje treba unositi u inventare iz stavka 1. je jedna godina između 2008. i 2010. Međutim, za prioritetne ili onečišćujuće tvari na koje se odnosi Direktiva 91/414/EEZ, vrijednosti koje treba unositi mogu se izračunati i kao prosjek 2008., 2009. i 2010. godine. 3. Inventare sastavljene u skladu sa stavkom 1. ovog članka, koji uključuju i odgovarajuća referentna razdoblja, države članice šalju Komisiji u skladu sa zahtjevima u pogledu izvješćivanja prema članku 15. stavku 1. Direktive 2000/60/EZ. 4. Države članice ažuriraju svoje inventare u sklopu preispitivanja analiza navedenih u članku 5. stavku 2. Direktive 2000/60/EZ. Referentno razdoblje za utvrđivanje vrijednosti u ažuriranim inventarima je godina prije godine u kojoj analiza mora biti završena. Za prioritetne ili onečišćujuće tvari na koje se odnosi Direktiva 91/414/EEZ vrijednosti koji se unose u inventar mogu se izračunati kao prosjek tijekom tri godine prije završetka te analize. Države članice objavljuju ažurirane inventare u svojim ažuriranim planovima upravljanja vodnim područjima kako su utvrđeni u članku 13. stavku 7. Direktive 2000/60/EZ. 5. Do 2018. godine Komisija mora provjeriti napreduju li emisije, ispuštanja i gubici kako su prikazani u inventaru prema ispunjenju ciljeva smanjenja ili prestanka utvrđenih u članku 4. stavku 1. točki (a) iv. Direktive 2000/60/EZ, podložno članku 4. stavcima 4. i 5. te Direktive. 6. Tehničke smjernice za izradu inventarâ usvajaju se u skladu s regulatornim postupkom spomenutim u članku 9. stavku 2. ove Direktive. |
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Članak 6. Prekogranično onečišćenje
|
Prekogranično onečišćenje 1. Država članica prekoračenjem SKO-a ne krši svoje obveze prema ovoj Direktivi ako može dokazati da:
|
|
Članak 7. Izvješćivanje i preispitivanje
|
Izvješćivanje i preispitivanje 1. Na temelju izvješćâ država članica, uključujući izvješća u skladu s člankom 12. Direktive 2000/60/EZ, a posebno onih o prekograničnom onečišćenju, Komisija preispituje postoji li potreba za izmjenom postojećih akata kao i potreba za dodatnim posebnim mjerama na razini Zajednice, kao na primjer kontrole emisija. 2. Komisija izvješćuje Europski parlament i Vijeće, u kontekstu izvješća pripremljenog u skladu s člankom 18. stavkom 1. Direktive 2000/60/EZ, o:
|
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Article 7a Coordination
|
|
|
Članak 8. Preispitivanje Priloga X. Direktivi 2000/60/EZ
|
Članak 8. Preispitivanje Priloga X. Direktivi 2000/60/EZ U okviru revizije Priloga X. Direktivi 2000/60/EZ, kako je predviđeno u članku 16. stavku 4. te Direktive, Komisija između ostalog razmatra tvari određene u Prilogu III. ovoj Direktivi, kako bi ih eventualno utvrdila kao prioritetne tvari ili prioritetne opasne tvari. O rezultatima ovog preispitivanja Komisija treba obavijestiti Europski parlament i Vijeće do 13. siječnja 2011. Uz to izvješće Komisija će prema potrebi dostaviti relevantne prijedloge, posebno prijedloge za utvrđivanje novih prioritetnih tvari ili prioritetnih opasnih tvari ili za utvrđivanje određenih prioritetnih tvari kao prioritetnih opasnih tvari i za utvrđivanje odgovarajućih SKO-a za površinske vode, sedimente ili biotu, ovisno o slučaju. |
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Article 8a Specific provisions for certain substances
|
|
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Article 8b Watch list
|
|
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Article 8c Specific provisions for pharmaceutical substances
|
Article 8c
Specific provisions for pharmaceutical substances
Pursuant to Article 16(9) of Directive 2000/60/EC, and where appropriate on the basis of the outcome of its 2013 study on the risks posed by medicinal products in the environment and of other relevant studies and reports, the Commission shall, as far as possible within two years from 13 September 2013 develop a strategic approach to pollution of water by pharmaceutical substances. That strategic approach shall, where appropriate, include proposals enabling, to the extent necessary, the environmental impacts of medicines to be taken into account more effectively in the procedure for placing medicinal products on the market. In the framework of that strategic approach, the Commission shall, where appropriate, by 14 September 2017 propose measures to be taken at Union and/or Member State level, as appropriate, to address the possible environmental impacts of pharmaceutical substances, particularly those referred to in Article 8b(1), with a view to reducing discharges, emissions and losses of such substances into the aquatic environment, taking into account public health needs and the cost-effectiveness of the measures proposed.
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Article 8d River basin specific pollutants
|
|
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Članak 9. Postupak Odbora
|
Članak 9. Postupak Odbora 1. Komisiji pomaže Odbor iz članka 21. stavka 1. Direktive 2000/60/EZ. 2. Kod upućivanja na ovaj stavak, primjenjuju se članci 5. i 7. Odluke 1999/468/EZ, uzimajući u obzir odredbe njezinog članka 8. Rok iz članka 5. stavka 6. Odluke 1999/468/EZ je tri mjeseca. 3. Kod upućivanja na ovaj stavak, primjenjuju se članak 5.a stavci 1. do 4. i članak 7. Odluke 1999/468/EZ, uzimajući u obzir odredbe njezinog članka 8. |
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Article 9a Exercise of the delegation
|
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Članak 11. Izmjena Direktiva 82/176/EEZ, 83/513/EEZ, 84/156/EEZ, 84/491/EEZ i 86/280/EEZ
|
Članak 11. Izmjena Direktiva 82/176/EEZ, 83/513/EEZ, 84/156/EEZ, 84/491/EEZ i 86/280/EEZ 1. Prilog II. direktivama 82/176/EEZ, 83/513/EEZ, 84/156/EEZ, odnosno, 84/491/EEZ, briše se. 2. Rubrike B u odjeljcima I. do XI. Priloga II. Direktivi 86/280/EEZ brišu se. |
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Članak 12. Stavljanje izvan snage Direktiva 82/176/EEZ, 83/513/EEZ, 84/156/EEZ, 84/491/EEZ i 86/280/EEZ
|
Članak 12. Stavljanje izvan snage Direktiva 82/176/EEZ, 83/513/EEZ, 84/156/EEZ, 84/491/EEZ i 86/280/EEZ 1. Direktive 82/176/EEZ, 83/513/EEZ, 84/156/EEZ, 84/491/EEZ i 86/280/EEZ ukidaju se s učinkom od 22. prosinca 2012. 2. Prije 22. prosinca 2012. države članice mogu provoditi praćenje i izvješćivati u skladu s člancima 5., 8. i 15. Direktive 2000/60/EZ, umjesto u skladu s direktivama iz stavka 1. ovog članka. |
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Članak 13. Prenošenje
|
Članak 13. Prenošenje 1. Države članice donose zakone i druge propise potrebne za usklađivanje s ovom Direktivom do 13. srpnja 2010. Kada države članice donose ove mjere, te mjere prilikom njihove službene objave sadrže uputu na ovu Direktivu ili se uz njih navodi takva uputa. Načine tog upućivanja određuju države članice. 2. Države članice Komisiji dostavljaju tekst glavnih odredaba nacionalnog prava koje donesu u području na koje se odnosi ova Direktiva. |
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Članak 14. Stupanje na snagu
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Članak 14. Stupanje na snagu Ova Direktiva stupa na snagu dvadesetog dana od dana objave u Službenom listu Europske unije. |
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Članak 15. Adresati
|
Adresati Ova je Direktiva upućena državama članicama.
Sastavljeno u Strasbourgu 16. prosinca 2008.
Za Europski parlament
Predsjednik
H.-G. PÖTTERING
Za Vijeće
Predsjednik
B. LE MAIRE
(1) SL C 97, 28.4.2007., str. 3.
(2) Mišljenje Europskog parlamenta od 22. svibnja 2007. (SL C 102 E, 24.4.2008., str. 90.), Zajedničko stajalište Vijeća od 20. prosinca 2007. (SL C 71 E, 18.3.2008., str. 1.) i Stajalište Europskog parlamenta od 17. lipnja 2008. (još nije objavljeno u Službenom listu). Odluka Vijeća od 20. listopada 2008.
(3) SL L 242, 10.9.2002., str. 1.
(4) SL L 327, 22.12.2000., str. 1.
(5) SL L 331, 15.12.2001., str. 1.
(6) SL L 181, 4.7.1986., str. 16.
(7) SL L 81, 27.3.1982., str. 29.
(8) SL L 291, 24.10.1983., str. 1.
(9) SL L 74, 17.3.1984., str. 49.
(10) SL L 274, 17.10.1984., str. 11.
(11) SL L 330, 5.12.1998., str. 32.
(12) SL L 33, 4.2.2006., str. 1.
(13) SL L 230, 19.8.1991., str. 1.
(14) SL L 24, 29.1.2008., str. 8.
(15) SL L 227, 8.9.1993., str. 9.
(16) SL L 123, 24.4.1998., str. 1.
(17) SL L 396, 30.12.2006., str. 1.; ispravljena verzija u SL L 136, 29.5.2007., str. 3.
(18) SL C 321., 31.12.2003., str. 1.
(19) SL L 184., 17.7.1999., str. 23.
PRILOG I. STANDARDI KVALITETE OKOLIŠA ZA PRIORITETNE TVARI I ODREĐENE DRUGE ONEČIŠĆUJUĆE TVARI DIO A: STANDARDI KVALITETE OKOLIŠA (SKO)
|
GP
|
:
|
godišnji prosjek;
|
|
MDK
|
:
|
najveća dopuštena koncentracija.
|
|
Jedinica
|
:
|
[μg/l]
|
|
(1)
|
(2)
|
(3)
|
(4)
|
(5)
|
(6)
|
(7)
|
|
Br.
|
Naziv tvari
|
CAS broj (1)
|
GP-SKO (2)
Kopnene površinske vode (3)
|
GP-SKO (2)
Druge površinske vode
|
MDK-SKO (4)
Kopnene površinske vode (3)
|
MDK-SKO (4)
Druge površinske vode
|
|
(1)
|
Alaklor
|
15972-60-8
|
0,3
|
0,3
|
0,7
|
0,7
|
|
(2)
|
Antracen
|
120-12-7
|
0,1
|
0,1
|
0,4
|
0,4
|
|
(3)
|
Atrazin
|
1912-24-9
|
0,6
|
0,6
|
2,0
|
2,0
|
|
(4)
|
Benzen
|
71-43-2
|
10
|
8
|
50
|
50
|
|
(5)
|
Bromirani difenileter (5)
|
32534-81-9
|
0,0005
|
0,0002
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(6)
|
Kadmij i njegovi spojevi
(ovisno o klasama tvrdoće vode) (6)
|
7440-43-9
|
≤ 0,08 (klasa 1)
|
0,2
|
≤ 0,45 (klasa 1)
|
≤ 0,45 (klasa 1)
|
|
0,08 (klasa 2)
|
0,45 (klasa 1)
|
0,45 (klasa 1)
|
|
0,09 (klasa 3)
|
0,6 (klasa 3)
|
0,6 (klasa 3)
|
|
0,15 (klasa 4)
|
0,9 (klasa 4)
|
0,9 (klasa 4)
|
|
0,25 (klasa 5)
|
1,5 (klasa 5)
|
1,5 (klasa 5)
|
|
(6a)
|
Ugljikov tetraklorid (7)
|
56-23-5
|
12
|
12
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(7)
|
C10-13 kloroalkani
|
85535-84-8
|
0,4
|
0,4
|
1,4
|
1,4
|
|
(8)
|
Klorofenvinfos
|
470-90-6
|
0,1
|
0,1
|
0,3
|
0,3
|
|
(9)
|
Klorpirifos (klorpirifos etil)
|
2921-88-2
|
0,03
|
0,03
|
0,1
|
0,1
|
|
(9a)
|
Ciklodienski pesticidi:
|
|
Σ = 0,01
|
Σ = 0,005
|
ne primjenjuje se
|
ne primjenjuje se
|
|
Aldrin (7)
|
309-00-2
|
|
Dieldrin (7)
|
60-57-1
|
|
Endrin (7)
|
72-20-8
|
|
Izodrin (7)
|
465-73-6
|
|
(9b)
|
DDT ukupno (7)
(8)
|
ne primjenjuje se
|
0,025
|
0,025
|
ne primjenjuje se
|
ne primjenjuje se
|
|
para-para-DDT (7)
|
50-29-3
|
0,01
|
0,01
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(10)
|
1,2-dikloroetan
|
107-06-2
|
10
|
10
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(11)
|
Diklorometan
|
75-09-2
|
20
|
20
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(12)
|
Di(2-etilheksil)ftalat (DEHP)
|
117-81-7
|
1,3
|
1,3
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(13)
|
Diuron
|
330-54-1
|
0,2
|
0,2
|
1,8
|
1,8
|
|
(14)
|
Endosulfan
|
115-29-7
|
0,005
|
0,0005
|
0,01
|
0,004
|
|
(15)
|
Fluoranten
|
206-44-0
|
0,1
|
0,1
|
1
|
1
|
|
(16)
|
Heksaklorobenzen
|
118-74-1
|
0,01 (9)
|
0,01 (9)
|
0,05
|
0,05
|
|
(17)
|
Heksaklorobutadien
|
87-68-3
|
0,1 (9)
|
0,1 (9)
|
0,6
|
0,6
|
|
(18)
|
Heksaklorocikloheksan
|
608-73-1
|
0,02
|
0,002
|
0,04
|
0,02
|
|
(19)
|
Izoproturon
|
34123-59-6
|
0,3
|
0,3
|
1,0
|
1,0
|
|
(20)
|
Olovo i njegovi spojevi
|
7439-92-1
|
7,2
|
7,2
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(21)
|
Živa i njezini spojevi
|
7439-97-6
|
0,05 (9)
|
0,05 (9)
|
0,07
|
0,07
|
|
(22)
|
Naftalen
|
91-20-3
|
2,4
|
1,2
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(23)
|
Nikal i njegovi spojevi
|
7440-02-0
|
20
|
20
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(24)
|
Nonilfenol (4-nonilfenol)
|
104-40-5
|
0,3
|
0,3
|
2,0
|
2,0
|
|
(25)
|
Oktilfenol (4-(1,1’,3,3’-tetrametilbutil)fenol)
|
140-66-9
|
0,1
|
0,01
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(26)
|
Pentaklorbenzen
|
608-93-5
|
0,007
|
0,0007
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(27)
|
Pentaklorfenol
|
87-86-5
|
0,4
|
0,4
|
1
|
1
|
|
(28)
|
Poliaromatski ugljikovodici (PAH) (10)
|
ne primjenjuje se
|
ne primjenjuje se
|
ne primjenjuje se
|
ne primjenjuje se
|
ne primjenjuje se
|
|
Benzo(a)piren
|
50-32-8
|
0,05
|
0,05
|
0,1
|
0,1
|
|
Benzo(b)fluoranten
|
205-99-2
|
Σ = 0,03
|
Σ = 0,03
|
ne primjenjuje se
|
ne primjenjuje se
|
|
Benzo(k)fluoranten
|
207-08-9
|
|
Benzo(g,h,i)perilen
|
191-24-2
|
Σ = 0,002
|
Σ = 0,002
|
ne primjenjuje se
|
ne primjenjuje se
|
|
Indeno(1,2,3-cd)piren
|
193-39-5
|
|
(29)
|
Simazin
|
122-34-9
|
1
|
1
|
4
|
4
|
|
(29a)
|
Tetrakloretilen (7)
|
127-18-4
|
10
|
10
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(29b)
|
Trikloroetilen (7)
|
79-01-6
|
10
|
10
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(30)
|
Tributilkositreni spojevi (Tributilkositar-kation)
|
36643-28-4
|
0,0002
|
0,0002
|
0,0015
|
0,0015
|
|
(31)
|
Triklorobenzeni
|
12002-48-1
|
0,4
|
0,4
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(32)
|
Triklorometan
|
67-66-3
|
2,5
|
2,5
|
ne primjenjuje se
|
ne primjenjuje se
|
|
(33)
|
Trifluralin
|
1582-09-8
|
0,03
|
0,03
|
ne primjenjuje se
|
ne primjenjuje se
|
DIO B: PRIMJENA STANDARDÂ KVALITETE OKOLIŠA ODREĐENIH U DIJELU A 1. Stupci 4. i 5. u tablici: za bilo koje vodno tijelo površinskih voda primjena GP-SKO znači, za svaku reprezentativnu točku praćenja u vodnom tijelu, da aritmetička sredina koncentracija izmjerenih u različito vrijeme tijekom godine ne prelazi standard. Izračun aritmetičke sredine, upotrijebljena analitička metoda i, ako nema odgovarajuće metode analize koja zadovoljava minimalne kriterije učinkovitosti, metoda primjene SKO-a, moraju biti u skladu s provedbenim aktima o usvajanju tehničkih specifikacija za praćenje kemijskog stanja i kvalitetu rezultata analize, u skladu s Direktivom 2000/60/EZ. 2. Stupci 6. i 7. u tablici: za bilo koje vodno tijelo površinskih voda primjena MDK-SKO znači da koncentracije izmjerene u bilo kojoj reprezentativnoj točki praćenja u vodnom tijelu ne prelaze standard. Međutim, u skladu s odjeljkom 1.3.4. Priloga V. Direktivi 2000/60 EZ države članice mogu uvesti statističke metode, kao što je izračun percentila, kako bi osigurale prihvatljivu razinu pouzdanosti i preciznosti za određivanje usklađenosti s MDK-SKO. Ako to učine, te statističke metode moraju biti u skladu s detaljnim pravilima utvrđenima u skladu s regulatornim postupkom iz članka 9. stavka 2. ove Direktive. 3. Uz izuzetak kadmija, olova, žive i nikla, (dalje u tekstu „metali”), SKO-i utvrđeni u ovom Prilogu izražavaju se kao ukupne koncentracije u cijelom uzorku vode. U slučaju metala SKO se odnosi na otopljene koncentracije, tj. otopljenu fazu uzorka vode dobivenu filtriranjem kroz filtar 0,45 μm ili nekom drugom ekvivalentnom predobradom. Pri ocjenjivanju rezultata praćenja stanja u odnosu na SKO države članice mogu uzeti u obzir:
|
|
ANNEX I
|
▼M1
ANNEX I
▼M2
ENVIRONMENTAL QUALITY STANDARDS (EQS) FOR PRIORITY SUBSTANCES IN SURFACE WATERS
PART A: ENVIRONMENTAL QUALITY STANDARDS
|
(1)
|
(2)
|
(3)
|
(4)
|
(5)
|
(6)
|
(7)
|
(8)
|
(9)
|
(10)
|
(11)
|
(12)
|
(13)
|
|
Entry No
|
Name of substance
|
Category of substances
|
CAS number (1)
|
EU number (2)
|
AA-EQS (3) Inland surface waters (4)
[μg/l]
|
AA-EQS (3)
Other surface waters
[μg/l]
|
MAC-EQS (5)
Inland surface waters (4)
[μg/l]
|
MAC-EQS (5)
Other surface waters
[μg/l]
|
EQS
Biota (6)
[μg/kg wet weight]
or EQS Sediment [μg /kg dry weight] where so indicated
|
Identified as a priority hazardous substance
|
Identified as an Ubiquitous Persistent, Bioaccumulative and Toxic (uPBT) substance
|
Identified as a substance that tends to accumulate in sediment and/or biota
|
|
(1)
|
The substance Alachlor has been moved to Part C of Annex II
|
|
(2)
|
Anthracene
|
Industrial substances
|
120-12-7
|
204-371-1
|
0,1
|
0,1
|
0,1
|
0,1
|
|
X
|
|
X
|
|
(3)
|
The substance Atrazine has been moved to Part C of Annex II
|
|
(4)
|
Benzene
|
Industrial substances
|
71-43-2
|
200-753-7
|
10
|
8
|
50
|
50
|
|
|
|
|
|
(5)
|
Brominated diphenylethers (7)
|
Industrial substances
|
not applicable
|
not applicable
|
|
|
0,14
|
0,014 (7)
|
0,00028 (7)
|
X (8)
|
X
|
X
|
|
(6)
|
Cadmium and its compounds
(depending on water hardness classes) (9)
|
Metals
|
7440-43-9
|
231-152-8
|
≤ 0,08 (Class 1)
0,08 (Class 2)
0,09 (Class 3)
0,15 (Class 4)
0,25 (Class 5)
|
0,2
|
≤ 0,45 (Class 1)
0,45 (Class 2)
0,6 (Class 3)
0,9 (Class 4)
1,5 (Class 5)
|
≤ 0,45 (Class 1)
0,45 (Class 2)
0,6 (Class 3)
0,9 (Class 4)
1,5 (Class 5)
|
|
X
|
|
X
|
|
(6a)
|
The substance Carbon tetrachloride has been moved to Part C of Annex II
|
|
(7)
|
C10-13 Chloroalkanes (10)
|
Industrial substances
|
85535-84-8
|
287-476-5
|
0,4
|
0,4
|
1,4
|
1,4
|
|
X
|
|
X
|
|
(8)
|
The substance Chlorfenvinphos has been moved to Part C of Annex II
|
|
(9)
|
Chlorpyrifos (Chlorpyrifos-ethyl)
|
Pesticides – organophosphate
|
2921-88-2
|
220-864-4
|
4,6 × 10-4
|
4,6 × 10-5
|
0,0026
|
5,2 × 10-4
|
|
X
|
X
|
X
|
|
(9a)
|
Cyclodiene pesticides:
Aldrin
Dieldrin
Endrin
Isodrin
|
Pesticides – organochlorine
|
309-00-2
60-57-1
72-20-8
465-73-6
|
206-215-8
200-484-5
200-775-7
207-366-2
|
Σ = 0,01
|
Σ = 0,005
|
not applicable
|
not applicable
|
|
X
|
|
|
|
(9b)
|
DDT total (11)
|
Pesticides – organochlorine
|
not applicable
|
not applicable
|
0,025
|
0,025
|
not applicable
|
not applicable
|
|
X
|
|
|
|
|
para-para-DDT
|
|
50-29-3
|
200-024-3
|
0,01
|
0,01
|
not applicable
|
not applicable
|
|
X
|
|
|
|
(10)
|
1,2-Dichloroethane
|
Industrial substances
|
107-06-2
|
203-458-1
|
10
|
10
|
not applicable
|
not applicable
|
|
X
|
|
|
|
(11)
|
Dichloromethane
|
Industrial substances
|
75-09-2
|
200-838-9
|
20
|
20
|
not applicable
|
not applicable
|
|
|
|
|
|
(12)
|
Di(2-ethylhexyl)-phthalate (DEHP)
|
Industrial substances
|
117-81-7
|
204-211-0
|
1,3
|
1,3
|
not applicable
|
not applicable
|
|
X
|
|
X
|
|
(13)
|
Diuron
|
Pesticides – herbicide
|
330-54-1
|
206-354-4
|
0,049
|
0,0049
|
0,27
|
0,054
|
|
|
|
|
|
(14)
|
Endosulfan
|
Pesticides – organochlorine
|
115-29-7
|
204-079-4
|
0,005
|
0,0005
|
0,01
|
0,004
|
|
X
|
|
|
|
(15)
|
Fluoranthene
|
Industrial substances
|
206-44-0
|
205-912-4
|
7,62 × 10-4
|
7,62 × 10-4
|
0,12
|
0,012
|
6,1
|
X
|
X
|
X
|
|
(16)
|
Hexachlorobenzene
|
Pesticides – organochlorine
|
118-74-1
|
204-273-9
|
|
|
0,5
|
0,05
|
8 fw fish
1 sw fish
|
X
|
|
X
|
|
(17)
|
Hexachlorobutadiene
|
Industrial substances (solvents)
|
87-68-3
|
201-765-5
|
9,5 x 10-4
|
9,5 × 10-4
|
0,6
|
0,06
|
21
|
X
|
|
X
|
|
(18)
|
Hexachlorocyclohexane
|
Pesticides – insecticides
|
608-73-1
|
210-168-9
|
0,02
|
0,002
|
0,04
|
0,02
|
|
X
|
|
X
|
|
(19)
|
Isoproturon
|
Pesticides – herbicide
|
34123-59-6
|
251-835-4
|
0,3
|
0,3
|
1,0
|
1,0
|
|
|
|
|
|
(20)
|
Lead and its compounds
|
Metals
|
7439-92-1
|
231-100-4
|
1,2 (12)
|
1,3
|
14
|
14
|
|
X
|
|
X
|
|
(21)
|
Mercury and its compounds
|
Metals
|
7439-97-6
|
231-106-7
|
|
|
0,07
|
0,07
|
11
|
X
|
X
|
X
|
|
(22)
|
Naphthalene
|
Industrial substances
|
91-20-3
|
202-049-5
|
2
|
2
|
130
|
130
|
|
|
|
|
|
(23)
|
Nickel and its compounds
|
Metals
|
7440-02-0
|
231-111-4
|
2 (12)
|
3,1
|
8,2
|
8,2
|
|
|
|
|
|
(24)
|
Nonylphenols (13) (4-Nonylphenol)
|
Industrial substances
|
see footnote 13
|
see footnote 13
|
0,037
|
0,0018
|
2,1
|
0,17
|
|
X
|
|
|
|
(25)
|
Octylphenols (14) ((4-(1,1’,3,3’-tetramethylbutyl)-phenol))
|
Industrial substances
|
see footnote 14
|
see footnote 14
|
0,1
|
0,01
|
not applicable
|
not applicable
|
|
X
|
|
|
|
(26)
|
Pentachlorobenzene
|
Industrial substances
|
608-93-5
|
210-172-0
|
0,007
|
0,0007
|
not applicable
|
not applicable
|
|
X
|
|
X
|
|
(27)
|
Pentachlorophenol
|
Pesticides – organochlorine
|
87-86-5
|
201-778-6
|
0,4
|
0,4
|
1
|
1
|
|
X
|
|
|
|
(28)
|
Polyaromatic hydrocarbons (PAHs) (15)
|
Combustion products
|
not applicable
|
not applicable
|
not applicable
|
not applicable
|
not applicable
|
not applicable
|
Sum of Benzo(a)pyrene equivalents 0,6 (16)
|
X
|
X
|
X
|
|
|
Benzo(a)pyrene
|
|
50-32-8
|
200-028-5
|
|
|
0,5
|
0,05
|
0,6
|
|
|
|
|
Benzo(b)fluoranthene
|
|
205-99-2
|
205-911-9
|
|
|
0,017
|
0,017
|
see footnote 16
|
|
|
|
|
Benzo(k)fluoranthene
|
|
207-08-9
|
205-916-6
|
|
|
0,017
|
0,017
|
see footnote 16
|
|
|
|
|
|
Benzo(g,h,i)perylene
|
|
191-24-2
|
205-883-8
|
|
|
8,2 × 10-3
|
8,2 × 10-4
|
see footnote 16
|
|
|
|
|
Indeno(1,2,3-cd)pyrene
|
|
193-39-5
|
205-893-2
|
|
|
not applicable
|
not applicable
|
see footnote 16
|
|
|
|
|
|
Chrysene
|
|
218-01-9
|
205-923-4
|
|
|
0,07
|
0,007
|
see footnote 16
|
|
|
|
|
|
Benzo(a)anthracene
|
|
56-55-3
|
200-280-6
|
|
|
0,1
|
0,01
|
see footnote 16
|
|
|
|
|
Dibenz(a,h)anthracene
|
53-70-3
|
200-181-8
|
|
|
0,014
|
0,0014
|
see footnote 16
|
|
|
|
|
Fluoranthene
|
|
206-44-0
|
205-912-4
|
|
|
0,12
|
0,012
|
see footnote 16
|
|
|
|
|
(29)
|
The substance Simazine has been moved to Part C of Annex II
|
|
(29a)
|
Tetrachloroethylene
|
Industrial substances
|
127-18-4
|
204-825-9
|
10
|
10
|
not applicable
|
not applicable
|
|
|
|
|
|
(29b)
|
Trichloroethylene
|
Industrial substances
|
79-01-6
|
201-167-4
|
10
|
10
|
not applicable
|
not applicable
|
|
X
|
|
|
|
(30)
|
Tributyltin compounds (17) (Tributyltin-cation)
|
Pesticides – biocide
|
36643-28-4
|
not applicable
|
0,0002
|
0,0002
|
0,0015
|
0,0015
|
1,6 (18)
|
X
|
X
|
X
|
|
(31)
|
The substance Trichlorobenzenes has been moved to Part C of Annex II
|
|
(32)
|
Trichloromethane
|
Industrial substances
|
67-66-3
|
200-663-8
|
2,5
|
2,5
|
not applicable
|
not applicable
|
|
|
|
|
|
(33)
|
Trifluralin
|
Pesticides – herbicides
|
1582-09-8
|
216-428-8
|
0,03
|
0,03
|
not applicable
|
not applicable
|
|
X
|
|
|
|
(34)
|
Dicofol
|
Pesticides – organochlorine
|
115-32-2
|
204-082-0
|
4,45 × 10-3
|
0,185 × 10-3
|
not applicable (19)
|
not applicable (19)
|
111 fw fish
4,6 sw fish
|
X
|
|
X
|
|
(35)
|
Perfluorooctane sulfonic acid (PFOS) and its derivatives
|
Industrial substances
|
1763-23-1
|
217-179-8
|
Covered by substance group 65 (Per- and polyfluoroalkyl substances (PFAS) – sum of 25)
|
|
(36)
|
Quinoxyfen
|
Pesticides – fungicide
|
124495-18-7
|
not applicable
|
0,15
|
0,015
|
2,7
|
0,54
|
|
X
|
|
X
|
|
(37)
|
Dioxins and dioxin-like compounds (20)
|
Industrial byproducts
|
not applicable
|
not applicable
|
|
|
not applicable
|
not applicable
|
Sum of PCDDs+ PCDFs+ PCB-DLs
equivalents 3,5 × 10-5 (21)
|
X
|
X
|
X
|
|
(38)
|
Aclonifen
|
Pesticides – herbicide
|
74070-46-5
|
277-704-1
|
0,12
|
0,012
|
0,12
|
0,012
|
|
|
|
|
|
(39)
|
Bifenox
|
Pesticides – herbicide
|
42576-02-3
|
255-894-7
|
0,012
|
0,0012
|
0,04
|
0,004
|
|
|
|
|
|
(40)
|
Cybutryne
|
Pesticides – biocide
|
28159-98-0
|
248-872-3
|
0,0025
|
0,0025
|
0,016
|
0,016
|
|
|
|
|
|
(41)
|
Cypermethrin (22)
|
Pesticides – pyrethroid
|
52315-07-8
|
257-842-9
|
3 × 10-5
|
3 × 10-6
|
6 × 10-4
|
6 × 10-5
|
|
|
|
X
|
|
(42)
|
Dichlorvos
|
Pesticides – organophosphate
|
62-73-7
|
200-547-7
|
6 × 10-4
|
6 × 10-5
|
7 × 10-4
|
7 × 10-5
|
|
|
|
|
|
(43)
|
Hexabromocyclododecane (HBCDD) (23)
|
Industrial substances
|
See footnote 23
|
See footnote 23
|
4,6 × 10-4
|
2 × 10-5
|
0,5
|
0,05
|
90 fw fish
3,5 sw fish
|
X
|
X
|
X
|
|
(44)
|
Heptachlor and heptachlor epoxide
|
Pesticides – organochlorine
|
76-44-8 / 1024-57-3
|
200-962-3/ 213-831-0
|
1,7 × 10-7
|
1,7 × 10-7
|
3 × 10-4
|
3 × 10-5
|
0,013
|
X
|
X
|
X
|
|
(45)
|
Terbutryn
|
Pesticides – biocides
|
886-50-0
|
212-950-5
|
0,065
|
0,0065
|
0,34
|
0,034
|
|
|
|
|
|
(46)
|
17 alpha-ethinylestradiol (EE2)
|
Pharmaceuticals – estrogenic hormone
|
57-63-6
|
200-342-2
|
1,7 × 10-5
|
1,6 × 10-6
|
not derived
|
not derived
|
|
|
|
|
|
(47)
|
17 beta-estradiol (E2)
|
Pharmaceuticals – estrogenic hormone
|
50-28-2
|
200-023-8
|
0,00018
|
9 × 10-6
|
not derived
|
not derived
|
|
|
|
|
|
(48)
|
Acetamiprid
|
Pesticides – neonicotinoid
|
135410-20-7 / 160430-64-8
|
603-921-1
|
0,037
|
0,0037
|
0,16
|
0,016
|
|
|
|
|
|
(49)
|
Azithromycin
|
Pharmaceuticals – macrolide antibiotic
|
83905-01-5
|
617-500-5
|
0,019
|
0,0019
|
0,18
|
0,018
|
|
|
|
X
|
|
(50)
|
Bifenthrin
|
Pesticides – pyrethroid
|
82657-04-3
|
617-373-6
|
9,5 × 10-5
|
9,5 × 10-6
|
0,011
|
0,001
|
|
|
|
X
|
|
(51)
|
Bisphenol-A (BPA)
|
Industrial substances
|
80-05-7
|
201-245-8
|
1,7 x 10-4
|
1,7 x 10-4
|
130
|
51
|
0,025
|
X
|
|
|
|
(52)
|
Carbamazepine
|
Pharmaceuticals – anticonvulsant
|
298-46-4
|
206-062-7
|
2,5
|
0,25
|
1,6 × 103
|
160
|
|
|
|
|
|
(53)
|
Clarithromycin
|
Pharmaceuticals – macrolide antibiotic
|
81103-11-9
|
658-034-2
|
0,13
|
0,013
|
0,13
|
0,013
|
|
|
|
X
|
|
(54)
|
Clothianidin
|
Pesticides -neonicotinoid
|
210880-92-5
|
433-460-1
|
0,01
|
0,001
|
0,34
|
0,034
|
|
|
|
|
|
(55)
|
Deltamethrin
|
Pesticides – pyrethroid
|
52918-63-5
|
258-256-6
|
1,7 × 10-6
|
1,7 × 10-7
|
1,7 × 10-5
|
3,4 × 10-6
|
|
|
|
X
|
|
(56)
|
Diclofenac
|
Pharmaceuticals – anti-inflammatory
|
15307-86-5 / 15307-79-6
|
239-348-5 / 239-346-4
|
0,04
|
0,004
|
250
|
25
|
|
|
|
X
|
|
(57)
|
Erythromycin
|
Pharmaceuticals – macrolide antibiotic
|
114-07-8
|
204-040-1
|
0,5
|
0,05
|
1
|
0,1
|
|
|
|
X
|
|
(58)
|
Esfenvalerate
|
Pesticides – pyrethroid
|
66230-04-4
|
613-911-9
|
1,7 × 10-5
|
1,7 × 10-6
|
0,0085
|
0,00085
|
|
|
|
X
|
|
(59)
|
Estrone (E1)
|
Pharmaceuticals – estrogenic hormone
|
53-16-7
|
200-164-5
|
3,6 × 10-4
|
1,8 × 10-5
|
not derived
|
not derived
|
|
|
|
|
|
(60)
|
Glyphosate
|
Pesticides – herbicide
|
1071-83-6
|
213-997-4
|
0,1 (24)
86,7 (25)
|
8,67
|
not applicable (24)
398,6 (25)
|
39,86
|
|
|
|
|
|
(61)
|
Ibuprofen
|
Pharmaceuticals – anti-inflammatory
|
15687-27-1
|
239-784-6
|
0,14
|
0,014
|
|
|
|
|
|
X
|
|
(62)
|
Imidacloprid
|
Pesticides – neonicotinoid
|
138261-41-3 / 105827-78-9
|
428-040-8
|
0,0068
|
6,8 × 10-4
|
0,057
|
0,0057
|
|
|
|
|
|
(63)
|
Nicosulfuron
|
Pesticides – herbicide
|
111991-09-4
|
601-148-4
|
0,0087
|
8,7 × 10-4
|
0,23
|
0,023
|
|
|
|
|
|
(64)
|
Permethrin
|
Pesticides – pyrethroid
|
52645-53-1
|
258-067-9
|
2,7 × 10-4
|
2,7 × 10-5
|
0,0025
|
2,5 × 10-4
|
|
|
|
X
|
|
(65)
|
Per- and polyfluoroalkyl substances (PFAS) – sum of 25 (26) (29)
|
Industrial substances
|
not applicable
|
not applicable
|
Sum of PFOA equivalents 0,0044 (27)
|
Sum of PFOA equivalents 0,0044 (27)
|
not applicable
|
not applicable
|
Sum of PFOA equivalents 0,077 (27)
|
X
|
X
|
X
|
|
(66)
|
Silver
|
Metals
|
7440-22-4
|
231-131-3
|
0,01
|
0,006 (10‰ salinity)
0,17 (30‰ salinity)
|
0,022
|
not derived
|
|
|
|
|
|
(67)
|
Thiacloprid
|
Pesticides – neonicotinoid
|
111988-49-9
|
601-147-9
|
0,01
|
0,001
|
0,05
|
0,005
|
|
|
|
|
|
(68)
|
Thiamethoxam
|
Pesticides – neonicotinoid
|
153719-23-4
|
428-650-4
|
0,04
|
0,004
|
0,77
|
0,077
|
|
|
|
|
|
(69)
|
Triclosan
|
Pesticides – biocides
|
3380-34-5
|
222-182-2
|
0,02
|
0,002
|
0,02
|
0,002
|
|
|
|
|
|
(70)
|
Sum of active substances in the pesticides (28) listed in this table (29) (30)
|
Pesticides
|
not applicable
|
not applicable
|
0,2 (30)
|
|
|
|
|
|
|
|
(1)
CAS: Chemical Abstracts Service.
(2)
EU number: European Inventory of Existing Commercial Substances (EINECS) or European List of Notified Chemical Substances (ELINCS).
(3)
This parameter is the EQS expressed as an annual average value (AA-EQS). Unless otherwise specified, it applies to the total concentration of all substances and isomers.
(4)
Inland surface waters encompass rivers and lakes and related artificial or heavily modified water bodies.
(5)
This parameter is the EQS expressed as a maximum allowable concentration (MAC EQS). Unless otherwise specified, it applies to the total concentration of all substances and isomers. Where the MAC EQS are marked as ‘not applicable’, the AA EQS values are considered protective against short-term pollution peaks in continuous discharges since they are significantly lower than the values derived on the basis of acute toxicity.
(6)
If an EQS for biota or sediment is given, it, rather than the water EQS, shall be applied, without prejudice to Article 3(3) of this Directive allowing an alternative biota taxon, or another matrix, to be monitored instead, as long as the EQS applied provides an equivalent level of protection. Unless otherwise specified, it applies to the total concentration of all substances and isomers. Unless otherwise indicated, the biota EQS relate to fish. ‘fw fish’ indicates the biota EQS for freshwater fish monitored in inland waters; ‘sw fish’ indicates the biota EQS for saltwater fish monitored in other surface waters. For substances numbered 15 (Fluoranthene), 28 (PAHs), and 51 (Bisphenol-A) the biota EQS refers to crustaceans and molluscs. For the purpose of assessing chemical status, monitoring of Fluoranthene PAHs, and Bisphenol-A in fish is not appropriate. For substance number 37 (Dioxins and dioxin-like compounds), the biota EQS relates to fish, crustaceans and molluscs, in line with point 4.1.5 of Annex I to Commission Regulation (EU) 2023/915 (*).
(7)
For the group of priority substances covered by brominated diphenylethers (No 5), the EQS refer to the sum of the concentrations of congener numbers 28, 47, 99, 100, 153 and 154.
(8)
Tetra, Penta, Hexa, Hepta, Octa and Decabromodiphenylether (CAS numbers 40088-47-9, 32534-81-9, 36483-60-0, 68928-80-3, 32536-52-0, 1163-19-5, respectively).
(9)
For Cadmium and its compounds (No 6) the EQS values vary depending on the hardness of the water as specified in five class categories (Class 1: < 40 mg CaCO3/l, Class 2: 40 to < 50 mg CaCO3/l, Class 3: 50 to < 100 mg CaCO3/l, Class 4: 100 to < 200 mg CaCO3/l and Class 5: ≥ 200 mg CaCO3/l).
(10)
No indicative parameter is provided for this group of substances. The indicative parameter(s) shall be defined through the analytical method.
(11)
DDT total comprises the sum of the isomers 1,1,1 trichloro 2,2 bis (p chlorophenyl) ethane (CAS 50 29 3, EU 200 024 3); 1,1,1 trichloro 2 (o chlorophenyl) 2 (p chlorophenyl) ethane (CAS 789 02 6, EU 212 332 5); 1,1-dichloro 2,2 bis (p chlorophenyl) ethylene (CAS 72 55 9, EU 200 784 6); and 1,1 dichloro 2,2 bis (p chlorophenyl) ethane (CAS 72 54 8, EU 200 783 0).
(12)
These EQS refer to bioavailable concentrations of the substances.
(13)
Nonylphenol (CAS 25154-52-3, EU 246-672-0) including isomers 4-nonylphenol (CAS 104-40-5, EU 203-199-4) and 4-nonylphenol (branched) (CAS 84852-15-3, EU 284-325-5).
(14)
Octylphenol (CAS 1806-26-4, EU 217-302-5) including isomer 4-(1,1’,3,3’-tetramethylbutyl)-phenol (CAS 140-66-9, EU 205-426-2).
(15)
Benzo(a)pyrene (CAS 50-32-8) (RPF 1), benzo(b)fluoranthene (CAS 205-99-2) (RPF 0,1 ), benzo(k)fluoranthene (CAS 207-08-9) (RPF 0,1 ), benzo(g,h,i)perylene (CAS 191-24-2) (RPF 0), indeno(1,2,3-cd)pyrene (CAS 193-39-5) (RPF 0,1 ), chrysene (CAS 218-01-9) (RPF 0,01 ), benzo(a)anthracene (CAS 56-55-3) (RPF 0,1 ), dibenz(a,h)anthracene (CAS 53-70-3) (RPF 1) and fluoranthene (CAS 206-44-0) (RPF 0,01 ). Fluoranthene also appears separately in row 15. The PAHs anthracene and naphthalene are listed only separately because no RPF is available.
(16)
For the group of polyaromatic hydrocarbons (PAHs) (No 28), the biota EQS refers to the sum of the concentrations of eight of the nine PAHs listed in footnote 15 expressed as benzo(a)pyrene equivalents based on the carcinogenic potencies of the substances relative to that of benzo(a)pyrene, i.e. the RPFs in footnote 15. Benzo(g,h,i)perylene does not need to be measured in biota for the purposes of determining compliance with the overall biota EQS. The biota EQS for fluoranthene in row 15 must also be complied with.
(17)
Tributyltin compounds including tributyltin-cation (CAS 36643-28-4).
(19)
There is insufficient information available to set a MAC-EQS for these substances.
(20)
This refers to the following compounds:
7 polychlorinated dibenzo-p-dioxins (PCDDs): 2,3,7,8-T4CDD (CAS 1746-01-6, EU 217-122-7), 1,2,3,7,8-P5CDD (CAS 40321-76-4), 1,2,3,4,7,8-H6CDD (CAS 39227-28-6), 1,2,3,6,7,8-H6CDD (CAS 57653-85-7), 1,2,3,7,8,9-H6CDD (CAS 19408-74-3), 1,2,3,4,6,7,8-H7CDD (CAS 35822-46-9), 1,2,3,4,6,7,8,9-O8CDD (CAS 3268-87-9)
10 polychlorinated dibenzofurans (PCDFs): 2,3,7,8-T4CDF (CAS 51207-31-9), 1,2,3,7,8-P5CDF (CAS 57117-41-6), 2,3,4,7,8-P5CDF (CAS 57117-31-4), 1,2,3,4,7,8-H6CDF (CAS 70648-26-9), 1,2,3,6,7,8-H6CDF (CAS 57117-44-9), 1,2,3,7,8,9-H6CDF (CAS 72918-21-9), 2,3,4,6,7,8-H6CDF (CAS 60851-34-5), 1,2,3,4,6,7,8-H7CDF (CAS 67562-39-4), 1,2,3,4,7,8,9-H7CDF (CAS 55673-89-7), 1,2,3,4,6,7,8,9-O8CDF (CAS 39001-02-0)
12 dioxin-like polychlorinated biphenyls (PCB-DLs): 3,3’,4,4’-T4CB (PCB 77, CAS 32598-13-3), 3,3’,4’,5-T4CB (PCB 81, CAS 70362-50-4), 2,3,3’,4,4’-P5CB (PCB 105, CAS 32598-14-4), 2,3,4,4’,5-P5CB (PCB 114, CAS 74472-37-0), 2,3’,4,4’,5-P5CB (PCB 118, CAS 31508-00-6), 2,3’,4,4’,5’-P5CB (PCB 123, CAS 65510-44-3), 3,3’,4,4’,5-P5CB (PCB 126, CAS 57465-28-8), 2,3,3’,4,4’,5-H6CB (PCB 156, CAS 38380-08-4), 2,3,3’,4,4’,5’-H6CB (PCB 157, CAS 69782-90-7), 2,3’,4,4’,5,5’-H6CB (PCB 167, CAS 52663-72-6), 3,3’,4,4’,5,5’-H6CB (PCB 169, CAS 32774-16-6), 2,3,3’,4,4’,5,5’-H7CB (PCB 189, CAS 39635-31-9).
(21)
For the group of Dioxins and dioxin-like compounds (No 37), the biota EQS refers to the sum of the concentrations of the substances listed in footnote 20 expressed as toxic equivalents based on the World Health Organisation 2005 Toxic Equivalence Factors.
(22)
CAS 52315-07-8 refers to an isomer mixture of cypermethrin, alpha-cypermethrin (CAS 67375-30-8, EU 257-842-9), beta-cypermethrin (CAS 65731-84-2, EU 265-898-0), theta-cypermethrin (CAS 71691-59-1) and zeta-cypermethrin (CAS 1315501-18-8, EU 257-842-9).
(23)
This refers to 1,3,5,7,9,11-Hexabromocyclododecane (CAS 25637-99-4, EU 247-148-4), 1,2,5,6,9,10-Hexabromocyclododecane (CAS 3194-55-6, EU 221-695-9), α-Hexabromocyclododecane (CAS 134237-50-6), β-Hexabromocyclododecane (CAS 134237-51-7) and γ-Hexabromocyclododecane (CAS 134237-52-8).
(24)
For freshwater used for the abstraction and preparation of drinking water.
(25)
For freshwater not used for the abstraction and preparation of drinking water.
(26)
This refers to the following compounds, listed with their CAS number, EU number and Relative Potency Factor (RPF):
Perfluorooctanoic acid (PFOA) (CAS 335-67-1, EU 206-397-9) (RPF 1), Perfluorooctane sulfonic acid (PFOS) (CAS 1763-23-1, EU 217-179-8) (RPF 2), Perfluorohexane sulfonic acid (PFHxS) (CAS 355-46-4, EU 206-587-1) (RPF 0,6 ), Perfluorononanoic acid (PFNA) (CAS 375-95-1, EU 206-801-3) (RPF 10), Perfluorobutane sulfonic acid (PFBS) (CAS 375-73-5, EU 206-793-1) (RPF 0,001 ), Perfluorohexanoic acid (PFHxA) (CAS 307-24-4, EU 206-196-6) (RPF 0,01 ), Perfluorobutanoic acid (PFBA) (CAS 375-22-4, EU 206-786-3) (RPF 0,05 ), Perfluoropentanoic acid (PFPeA) (CAS 2706-90-3, EU 220-300-7) (RPF 0,03 ), Perfluoropentane sulfonic acid (PFPeS) (CAS 2706-91-4, EU 220-301-2) (RPF 0,3005 ), Perfluorodecanoic acid (PFDA) (CAS 335-76-2, EU 206-400-3) (RPF 7), Perfluorododecanoic acid (PFDoDA or PFDoA) (CAS 307-55-1, EU 206-203-2) (RPF 3), Perfluoroundecanoic acid (PFUnDA or PFUnA) (CAS 2058-94-8, EU 218-165-4) (RPF 4), Perfluoroheptanoic acid (PFHpA) (CAS 375-85-9, EU 206-798-9) (RPF 0,505 ), Perfluorotridecanoic acid (PFTrDA) (CAS 72629-94-8, EU 276-745-2) (RPF 1,65 ), Perfluoroheptane sulfonic acid (PFHpS) (CAS 375-92-8, EU 206-800-8) (RPF 1,3 ), Perfluorodecane sulfonic acid (PFDS) (CAS 335-77-3, EU 206-401-9) (RPF 2), Perfluorotetradecanoic acid (PFTeDA) (CAS 376-06-7, EU 206-803-4) (RPF 0,3 ), Perfluorohexadecanoic acid (PFHxDA) (CAS 67905-19-5, EU 267-638-1) (RPF 0,02 ), Perfluorooctadecanoic acid (PFODA) (CAS 16517-11-6, EU 240-582-5) (RPF 0,02 ), 2,3,3,3-tetrafluoro-2-(heptafluoropropoxy)propionic acid (HFPO-DA) (CAS 13252-13-6) (RPF 0,06 ), 2,2,3-trifluoro-3-(1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propoxy)propanoic acid (CAS 919005-14-4) (RPF 0,03 ), 2- (Perfluorohexyl)ethyl alcohol (6:2 FTOH) (CAS 647-42-7, EU 211-477-1) (RPF 0,02 ), 2-(Perfluorooctyl)ethanol (8:2 FTOH) (CAS 678-39-7, EU 211-648-0) (RPF 0,04 ) and 2,2-difluoro-2-((2,2,4,5-tetrafluoro-5-(trifluoromethoxy)-1,3-dioxolan-4-yl)oxy) acetic acid (C6O4) (CAS 1190931-41-9) (RPF 0,06 ), Trifluoroacetic acid (TFA) (CAS 76-05-1, EU 200-929-3) (RPF 0,002 ).
(27)
For the group of PFAS (No 65), the EQS refer to the sum of the concentrations of the 25 PFAS listed in footnote 26 expressed as PFOA-equivalents based on the potencies of the substances relative to that of PFOA, i.e. the RPFs in footnote 26. The critical EQS is the biota EQS (relating to fish consumption) and must therefore be complied with. The AA-EQS are not equivalently protective.
(28)
‘Pesticides’ means plant protection products as referred to in Article 2 of Regulation (EC) No 1107/2009 and biocidal products as defined in Article 3 of Regulation (EU) No 528/2012.
(29)
The minimum performance criteria laid down in Directive 2009/90/EC apply to each individual substance within the group of substances but taking account of the need to quantify the contribution of each substance to the total concentration for comparison with the EQS.
(30)
With the following exceptions: the four pesticides to be monitored in biota or sediment, i.e. the substances numbered 16, 30, 34 and 44, and glyphosate.
(*) Commission Regulation (EU) 2023/915 of 25 April 2023 on maximum levels for certain contaminants in food and repealing Regulation (EC) No 1881/2006 (OJ L 119, 5.5.2023, p. 103, ELI: http://data.europa.eu/eli/reg/2023/915/oj).
|
▼B
PART B: APPLICATION OF THE EQS SET OUT IN PART A
|
1.
|
►M2
For any given surface water body, applying the AA-EQS means that, for each representative monitoring point within the water body, the arithmetic mean of the concentrations measured at different times during the year does not exceed the standard. ◄
The calculation of the arithmetic mean, the analytical method used and, where there is no appropriate analytical method meeting the minimum performance criteria, the method of applying an EQS must be in accordance with implementing acts adopting technical specifications for chemical monitoring and quality of analytical results, in accordance with Directive 2000/60/EC.
|
▼M1
|
2.
|
►M2
For any given surface water body, applying the MAC-EQS means that the measured concentration at any representative monitoring point within the water body does not exceed the standard. ◄
However, in accordance with Section 1.3.4 of Annex V to Directive 2000/60/EC, Member States may introduce statistical methods, such as a percentile calculation, to ensure an acceptable level of confidence and precision for determining compliance with the MAC-EQS. Where Member States do so, such statistical methods shall comply with detailed rules laid down in accordance with the examination procedure referred to in Article 9(2) of this Directive.
|
|
3.
|
The water EQS laid down in this Annex are expressed as total concentrations in the whole water sample.
By way of derogation from the first subparagraph, in the case of cadmium, lead, mercury and nickel (hereinafter ‘metals’), the water EQS refer to the dissolved concentration, i.e. the dissolved phase of a water sample obtained by filtration through a 0,45 μm filter or any equivalent pre-treatment, or, where specifically indicated, to the bioavailable concentration.
Member States may, when assessing the monitoring results against the relevant EQS, take into account:
(a)
natural background concentrations for metals and their compounds where such concentrations prevent compliance with the relevant EQS;
(b)
hardness, pH, dissolved organic carbon or other water quality parameters that affect the bioavailability of metals, the bioavailable concentrations being determined using appropriate bioavailability modelling.
|
|
|
ANNEX II ENVIRONMENTAL QUALITY STANDARDS FOR RIVER BASIN SPECIFIC POLLUTANTS
|
ANNEX II
ENVIRONMENTAL QUALITY STANDARDS FOR RIVER BASIN SPECIFIC POLLUTANTS
PART A: INDICATIVE LIST OF CATEGORIES OF RIVER BASIN SPECIFIC POLLUTANTS
1. Organohalogen compounds and substances which may form such compounds in the aquatic environment.
2. Organophosphorous compounds.
4. Substances and preparations, or the breakdown products of such, which have been proved to possess carcinogenic or mutagenic properties or properties which may affect steroidogenic, thyroid, reproduction or other endocrine-related functions in or via the aquatic environment.
5. Persistent hydrocarbons and persistent and bioaccumulable organic toxic substances.
7. Metals and their compounds.
8. Arsenic and its compounds.
9. Biocides and plant protection products.
10. Materials in suspension, including micro/nanoplastics
11. Microorganisms, genes or genetic material reflecting the presence of microorganisms resistant to antimicrobial agents, in particular microorganisms pathogenic to humans or livestock.
PART B: THE PROCEDURE FOR DERIVING ENVIRONMENTAL QUALITY STANDARDS FOR RIVER BASIN SPECIFIC POLLUTANTS
Methods used for the establishment of EQS for river basin specific pollutants shall include the following steps:
(a)
identification of the receptors and compartments or matrices at risk from the substance of concern;
(b)
collation and quality assessment of data on the properties of the substance of concern, including its (eco)toxicity, in particular from reports on laboratory, mesocosm and field studies which cover both chronic and acute effects in both fresh and saltwater environments;
(c)
extrapolation of (eco)toxicity data to no-effect or similar concentrations using deterministic or probabilistic methods, and selection and application of appropriate assessment factors to address uncertainties and derive EQS;
(d)
comparison of EQS for different receptors and compartments, and selection of critical EQS, i.e. the EQS that provides protection to the most sensitive receptor in the most relevant compartment or matrix.
PART C: REPOSITORY OF HARMONISED ENVIRONMENTAL QUALITY STANDARDS FOR RIVER BASIN SPECIFIC POLLUTANTS
|
Entry No
|
Name of substance
|
Category of substances
|
CAS number (1)
|
EU number (2)
|
AA-EQS (3)
Inland surface waters (4)
[μg/l]
|
AA-EQS (3)
Other surface waters
[μg/l]
|
MAC-EQS (5)
Inland surface waters (4)
[μg/l]
|
MAC-EQS (5)
Other surface waters
[μg/l]
|
EQS
Biota (6)
[μg/kg wet weight] or EQS Sediment where so indicated [μg /kg dry weight]
|
|
1
|
Alachlor (7)
|
Pesticides
|
15972-60-8
|
240-110-8
|
0,3
|
0,3
|
0,7
|
0,7
|
|
|
2
|
Carbon tetrachloride (7)
|
Industrial substances
|
56-23-5
|
200-262-8
|
12
|
12
|
not applicable
|
not applicable
|
|
|
3
|
Chlorfenvinphos (7)
|
Pesticides
|
470-90-6
|
207-432-0
|
0,1
|
0,1
|
0,3
|
0,3
|
|
|
4
|
Simazine (7)
|
Pesticides
|
122-34-9
|
204-535-2
|
1
|
1
|
4
|
4
|
|
|
5
|
Trichlorobenzenes (7)
|
Industrial substances – solvent
|
12002-48-1
|
234-413-4
|
0,4
|
0,4
|
not applicable
|
not applicable
|
|
|
6
|
Atrazine (7)
|
Pesticides – herbicides
|
1912-24-9
|
217-617-8
|
0,6
|
0,6
|
2,0
|
2,0
|
|
(1)
CAS: Chemical Abstracts Service.
(2)
EU number: European Inventory of Existing Commercial Substances (EINECS) or European List of Notified Chemical Substances (ELINCS).
(3)
This parameter is the EQS expressed as an annual average value (AA-EQS). Unless otherwise specified, it applies to the total concentration of all substances and isomers.
(4)
Inland surface waters encompass rivers and lakes and related artificial or heavily modified water bodies.
(5)
This parameter is the EQS expressed as a maximum allowable concentration (MAC EQS). Where the MAC EQS are marked as ‘not applicable’, the AA EQS values are considered protective against short-term pollution peaks in continuous discharges since they are significantly lower than the values derived on the basis of acute toxicity.
(6)
If a biota EQS is given, it, rather than the water EQS, shall be applied, without prejudice to Article 3(3) of this Directive allowing an alternative biota taxon, or another matrix, to be monitored instead, as long as the EQS applied provides an equivalent level of protection. Unless otherwise indicated, the biota EQS relate to fish.
(7)
Substance previously listed as a priority substance in Annex X to Directive 2000/60/EC or Annex I to Directive 2008/105/EC.
|
|
|
ANNEX III SUBSTANCES SUBJECT TO REVIEW FOR POSSIBLE IDENTIFICATION AS PRIORITY SUBSTANCES
|
ANNEX III
SUBSTANCES SUBJECT TO REVIEW FOR POSSIBLE IDENTIFICATION AS PRIORITY SUBSTANCES
|
Name of substance
|
CAS number (1)
|
EU number (2)
|
|
Sum of Bisphenols
|
not applicable
|
not applicable
|
|
Sum(s) of selected pesticides by mode of action
|
not applicable
|
not applicable
|
|
Sum(s) of selected pharmaceuticals by mode of action
|
not applicable
|
not applicable
|
(1)
CAS: Chemical Abstracts Service.
(2)
EU number: European Inventory of Existing Commercial Substances (EINECS) or European List of Notified Chemical Substances (ELINCS).
|
|
,
1.1 Reference
1.2 Utvrđeni zahtjevi
1.3 Povezani standardi
2. Utvrđeni zahtjevi
3. Povezani standardi
- Builddate: 10.05.2026 00:00:00 -Doknr: CELEX:32008L0105
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